Search | Engineering

订阅投稿

首页工程期刊工程焦点工程成就工程前沿关于我们 English

资源类型

期刊论文 797

会议视频 15

会议信息 1

年份

2024 1

2023 66

2022 68

2021 51

2020 49

2019 47

2018 39

2017 36

2016 33

2015 35

2014 34

2013 47

2012 54

2011 43

2010 65

2009 27

2008 33

2007 27

2006 8

2005 7

展开︾

关键词

天然气 11

吸附 9

能源 8

固体氧化物燃料电池 7

普光气田 7

勘探开发 6

页岩气 5

固体废物 4

天然气水合物 4

温室气体 4

资源化利用 4

中国 3

关键技术 3

创新 3

采油工程 3

SOFC 2

三相界面 2

中国近海 2

低碳 2

展开︾

检索范围：

排序：展示方式：

Lagrangian simulation of deposition of CO gas-solid sudden expansion flow

HUANG Dongping, DING Guoliang, QUACK Hans

《能源前沿（英文）》 2008年第2卷第2期页码 216-221 doi: 10.1007/s11708-008-0032-3

摘要： Freezing and blockage resulting from the deposition of solid CO formed because of sudden expansion of the downstream pipe during the release of CO through safety valves, will endanger the protected equipment. To overcome this problem, the characteristics of the CO gas-solid sudden expansion flow are studied by using the disperse Lagrangian model. A comparison of the calculated deposition of the solid CO with the experimental results shows that they are in reasonable agreement. The simulation results show that the size of the solid CO formed should not be in the range of 0.04–0.07 mm ( number 3.2–9.8). This can be achieved by using an appropriate flow cross section of the safety valve.

关键词： comparison gas-solid downstream blockage Lagrangian

HTML PDF 收藏

CFD simulation of jet behaviors in a binary gas-solid fluidized bed: comparisons with experiments

Pei PEI, Guiying WU, Bangting YU, Kai ZHANG, Jianchun JIANG, Dongsheng WEN,

《化学科学与工程前沿（英文）》 2010年第4卷第3期页码 242-249 doi: 10.1007/s11705-009-0277-3

摘要： Based on the experimental observation of the fluidization characteristics of solid mixtures (resin and rapeseed) with different densities and sizes, the jet behaviours of the binary system are simulated in a two-dimensional jetting fluidized bed 0.30 m in width and 2.00 m in height. A simple mathematical model, by introducing two additional force terms in both gas and particle phase momentum equations of Gidaspow’s inviscid two-fluid model, is used to explore the effects of jet gas velocity and mixture combination on the jet penetration depth in the fluidized bed with a binary system. Experimental results show that there is a fluidization velocity interval (-) for the resin-on-rapeseed (flotsam-on-jetsam) segregated bed. The simulated jet penetration depth increases with the increase of jet gas velocity and the volume fraction of the flotsam (resin), which is in fair agreement with experimental data. The above findings show that the hydrodynamic model of Brandani and Zhang (2006), by introducing the average physical properties from Goossens et al.(1971), can be used to predict the jet behaviors of a well-mixing binary system.

关键词： mathematical two-dimensional flotsam-on-jetsam fluidization velocity physical

HTML PDF 收藏

Influence of environmental temperature and relative humidity on photocatalytic oxidation of toluene on activated carbon fibers coated TiO

GUO Ting, BAI Zhipeng, WU Can, ZHU Tan

《环境科学与工程前沿（英文）》 2008年第2卷第2期页码 224-229 doi: 10.1007/s11783-008-0039-3

摘要： TiO supported on active carbon fiber (TiO/ACF), an absorbable photocatalyst, is a new kind of material applied in air purification. In this paper, the influence of environmental temperature (T) and relative humidity (RH) on the gas-solid adsorption of toluene and the photocatalytic oxidation (PCO) efficiency of adsorbed toluene on TiO/ACF were studied, and then, the purification capability of TiO/ACF was estimated. PCO results showed that although the PCO efficiency increased under high RH and T levels, the amount of adsorption of toluene decreased. Moreover, quantitative analysis results of intermediates indicated that more environmental risk emerged when PCO of toluene was carried out at higher environmental T and RH levels because more toxic intermediates would be accumulated on the TiO/ACF. So, it is significant to control the environmental T and RH conditions in the application of the PCO technique. T = 25°C and RH = 30% is the optimal condition for purifying toluene in our experimental system.

关键词： application gas-solid adsorption technique TiO/ACF experimental

HTML PDF 收藏

Particle-scale simulation of fluidized bed with immersed tubes

ZHAO Yongzhi, JIANG Maoqiang, CHENG Yi

《化学科学与工程前沿（英文）》 2008年第2卷第3期页码 341-345 doi: 10.1007/s11705-008-0046-8

摘要： In order to simulate gas-solids flows with complex geometry, the boundary element method was incorporated into the implementation of a combined model of computational fluid dynamics and discrete element method. The resulting method was employed to simulate hydrodynamics in a fluidized bed with immersed tubes. The transient simulation results showed particle and bubble dynamics. The bubble coalescence and break-up behavior when passing the immersed tubes was successfully predicted. The gas-solid flow pattern in the fluidized bed is changed greatly because of the immersed tubes. As particles and gas are come in contact with the immersed tubes, the gas bubbles will be deformed. The collisions between particles and tubes will make the tubes surrounded by air pockets most of the time and this is unfavorable for the heat transfer between particles and tubes.

关键词： unfavorable computational gas-solid particle discrete

HTML PDF 收藏

Dehydration of natural gas and biogas streams using solid desiccants: a review

Soheil Bahraminia, Mansoor Anbia, Esmat Koohsaryan

《化学科学与工程前沿（英文）》 2021年第15卷第5期页码 1050-1074 doi: 10.1007/s11705-020-2025-7

摘要： Natural gas and biogas are two mixtures that consist of methane as their main component. These two gas mixtures are usually saturated with water vapor, which cause many problems, such as damaging the gas processing equipment by increasing the gas’s corrosion potential or clogging the pipelines due to gas hydrate formation. Thus, removing water vapor from these gas streams is mandatory. In this review paper, the main dehydration methods have been overviewed, and scrutiny of the adsorption dehydration has been carried out. Furthermore, the most important solid desiccants and their improvements have been reviewed.

关键词： natural gas biogas dehydration adsorption solid desiccant

HTML PDF 收藏

Simulation of horizontal slug-flow pneumatic conveying with kinetic theory

GU Zhengmeng, GUO Liejin

《能源前沿（英文）》 2007年第1卷第3期页码 336-340 doi: 10.1007/s11708-007-0050-6

摘要： Wavelike slug-flow is a representative flow type in horizontal pneumatic conveying. Kinetic theory was introduced to establish a 3D kinetic numerical model for wavelike slug gas-solid flow in this paper. Wavelike motion of particulate slugs in horizontal pipes was numerically investigated. The formation and motion process of slugs and settled layer were simulated. The characteristics of the flow, such as pressure drop, air velocity distribution, slug length and settled layer thickness, and the detailed changing characteristics of slug length and settled layer thickness with air velocity were obtained. The results indicate that kinetic theory can represent the physical characteristics of the non-suspension dense phase flow of wavelike slug pneumatic conveying. The experiment in this paper introduced a new idea for the numerical calculation of slug-flow pneumatic conveying.

关键词： velocity distribution detailed slug-flow gas-solid theory

HTML PDF 收藏

Numerical simulation of two-dimensional spouted bed with draft plates by discrete element method

ZHAO Yongzhi, JIANG Maoqiang, CHENG Yi, JIN Yong

《化学科学与工程前沿（英文）》 2008年第2卷第1期页码 5-9 doi: 10.1007/s11705-008-0009-0

摘要： A discrete element method (DEM)-computational fluid dynamics (CFD) two-way coupling method was employed to simulate the hydrodynamics in a two-dimensional spouted bed with draft plates. The motion of particles was modeled by the DEM and the gas flow was modeled by the Navier-Stokes equation. The interactions between gas and particles were considered using a two-way coupling method. The motion of particles in the spouted bed with complex geometry was solved by combining DEM and boundary element method (BEM). The minimal spouted velocity was obtained by the BEM-DEM-CFD simulation and the variation of the flow pattern in the bed with different superficial gas velocity was studied. The relationship between the pressure drop of the spouted bed and the superficial gas velocity was achieved from the simulations. The radial profile of the averaged vertical velocities of particles and the profile of the averaged void fraction in the spout and the annulus were statistically analyzed. The flow characteristics of the gas-solid system in the two-dimensional spouted bed were clearly described by the simulation results.

关键词： annulus BEM-DEM-CFD simulation gas-solid two-dimensional relationship

HTML PDF 收藏

Polypropylene microplastics alter the cadmium adsorption capacity on different soil solid fractions

《环境科学与工程前沿（英文）》 2022年第16卷第1期页码 3-3 doi: 10.1007/s11783-021-1437-z

摘要：

Microplastics (MPs) are widely present in a variety of environmental media and have attracted more and more attention worldwide. However, the effect of MPs on the interaction between heavy metals and soil, especially in soil solid fraction level, is not well understood. In this study, batch experiments were performed to investigate the adsorption characteristics of Cd in bulk soil and three soil solid fractions (i.e. particulate organo matter (POM), organic-mineral compounds (OMC), and mineral) with or without polypropylene (PP) MPs.

关键词： Polypropylene microplastics Cadmium Adsorption POM OMC Mineral

HTML PDF 收藏

王军武：非均匀气固两相流本构关系建模及其验证（2020年1月10日）

王军武(高级职称)

2020年06月23日

关键词：过程工程研究

Atomistic simulations for adsorption and separation of flue gas in MFI zeolite and MFI/MCM-41 micro/mesoporous

Shengchi ZHUO, Yongmin HUANG, Jun HU, Honglai LIU

《化学科学与工程前沿（英文）》 2011年第5卷第2期页码 264-273 doi: 10.1007/s11705-010-1007-6

摘要： Adsorption of pure CO and N and separation of CO /N mixture in MFI zeolite and MFI/MCM-41 micro/mesoporous composite have been studied by using atomistic simulations. Fully atomistic models of MFI and MFI/MCM-41 are constructed and characterized. A bimodal pore size distribution is observed in MFI/MCM-41 from simulated small- and broad-angle X-ray diffraction patterns. The density of MFI/MCM-41 is lower than MFI, while its free volume and specific surface area are greater than MFI due to the presence of mesopores. CO is preferentially adsorbed than N , and thus, the loading and isosteric heat of CO are greater than N in both MFI and MFI/MCM-41. CO isotherm in MFI/MCM-41 is similar to that in MFI at low pressures, but resembles that in MCM-41 at high pressures. N shows similar amount of loading in MFI, MCM-41 and MFI/MCM-41. The selectivity of CO over N in the three adsorbents decreases in the order of MFI>MFI/MCM-41>MCM-41. With increasing pressure, the selectivity increases in MFI and MFI/MCM-41, but decreases in MCM-41. The self-diffusivity of CO and N in MFI decreases as loading increases, while in MFI/MCM-41, it first increases and then drops.

关键词： adsorption diffusion CO₂ flue gas zeolite micro/mesoporous composite

HTML PDF 收藏

Simultaneous analysis of five taste and odor compounds in surface water using solid-phase extractionand gas chromatography-mass spectrometry

Wenfeng SUN, Ruibao JIA, Baoyu GAO

《环境科学与工程前沿（英文）》 2012年第6卷第1期页码 66-74 doi: 10.1007/s11783-010-0257-3

摘要： In this paper, a method using solid-phase extraction (SPE) and gas chromatography-mass spectrometry (GC-MS) was developed to simultaneously analyze five taste and odor compounds in surface water, i.e., 2-methylisoborneol (2-MIB), 2,4,6-trichloroanisole (TCA), 2-isopropyl-3-methoxy pyrazine (IPMP), 2-isobutyl-3-methoxy pyrazine (IBMP), and -1,10-dimethyl- -9-decalol (geosmin, GSM). The mass spectrometry was operated in selective ion monitoring (SIM) mode. Three kinds of SPE columns and three eluting solvents were compared, the C18 column was chosen as optimum SPE column, and methanol was chosen as the optimum eluting solvent. It was found that the method showed good linearity in the range of 1–200 ng·L and gave detection limits of 0.5–1.5 ng·L for individual compounds. Good recoveries (93.5%–108%) and relative standard deviations (1.58%–7.31%) were also obtained. Additionally, concentrations of these taste and odor compounds in Jinan’s surface and drinking water were analyzed by applying this method, and the results showed that GSM and 2-MIB were the dominant taste and odor compounds in Jinan’s raw water.

关键词： solid-phase extraction (SPE) gas chromatography-mass spectrometry (GC-MS) taste and odor compounds surface water micropollutant

HTML PDF 收藏

鲁波娜：气固非均相反应器理论及多尺度模拟（2020年1月10日）

鲁波娜(高级职称)

2020年06月23日

关键词：过程工程研究

Part-load, startup, and shutdown strategies of a solid oxide fuel cell-gas turbine hybrid system

Yang LI, Yiwu WENG, Shilie WENG

《能源前沿（英文）》 2011年第5卷第2期页码 181-194 doi: 10.1007/s11708-011-0149-7

摘要： Current work on the performance of a solid oxide fuel cell (SOFC) and gas turbine hybrid system is presented. Each component model developed and applied is mathematically defined. The electrochemical performance of single SOFC with different fuels is tested. Experimental results are used to validate the SOFC mathematical model. Based on the simulation model, a safe operation regime of the hybrid system is accurately plotted first. Three different part-load strategies are introduced and used to analyze the part-load performance of the hybrid system using the safe regime. Another major objective of this paper is to introduce a suitable startup and shutdown strategy for the hybrid system. The sequences for the startup and shutdown are proposed in detail, and the system responses are acquired with the simulation model. Hydrogen is used instead of methane during the startup and shutdown process. Thus, the supply of externally generated steam is not needed for the reforming reaction. The gas turbine is driven by complementary fuel and supplies compressed air to heat up or cool down the SOFC stack operating temperature. The dynamic simulation results show that smooth cooling and heating of the cell stack can be accomplished without external electrical power.

关键词： solid oxide fuel cell (SOFC) hybrid system part-load strategy startup shutdown

HTML PDF 收藏

CO, N, and CO/N mixed gas injection for enhanced shale gas recovery and CO geological storage

《能源前沿（英文）》 2023年第17卷第3期页码 428-445 doi: 10.1007/s11708-023-0865-9

摘要： In this work, using fractured shale cores, isothermal adsorption experiments and core flooding tests were conducted to investigate the performance of injecting different gases to enhance shale gas recovery and CO₂ geological storage efficiency under real reservoir conditions. The adsorption process of shale to different gases was in agreement with the extended-Langmuir model, and the adsorption capacity of CO₂ was the largest, followed by CH_4, and that of N₂ was the smallest of the three pure gases. In addition, when the CO₂ concentration in the mixed gas exceeded 50%, the adsorption capacity of the mixed gas was greater than that of CH₄, and had a strong competitive adsorption effect. For the core flooding tests, pure gas injection showed that the breakthrough time of CO₂ was longer than that of N₂, and the CH₄ recovery factor at the breakthrough time (

R C H 4

) was also higher than that of N₂. The

R C H 4

of CO₂ gas injection was approximately 44.09%, while the

R C H 4

of N₂ was only 31.63%. For CO₂/N₂ mixed gas injection, with the increase of CO₂ concentration, the

R C H 4

increased, and the

R C H 4

for mixed gas CO₂/N₂ = 8:2 was close to that of pure CO₂, about 40.24%. Moreover, the breakthrough time of N₂ in mixed gas was not much different from that when pure N₂ was injected, while the breakthrough time of CO₂ was prolonged, which indicated that with the increase of N₂ concentration in the mixed gas, the breakthrough time of CO₂ could be extended. Furthermore, an abnormal surge of N₂ concentration in the produced gas was observed after N₂ breakthrough. In regards to CO₂ storage efficiency (

S s t o r a g e - C O 2

), as the CO₂ concentration increased,

S s t o r a g e - C O 2

also increased. The

S s t o r a g e - C O 2

of the pure CO₂ gas injection was about 35.96%, while for mixed gas CO₂/N₂ = 8:2,

S s t o r a g e - C O 2

was about 32.28%.

关键词： shale gas gas injection competitive adsorption enhanced shale gas recovery CO₂ geological storage

HTML PDF 收藏

metal ions onto metal–organic frameworks: implications for the ‘‘versatility’’ of these materials as solid

《化学科学与工程前沿（英文）》页码 1632-1642 doi: 10.1007/s11705-022-2187-6

摘要： Although metal–organic frameworks offer a new platform for developing versatile sorption materials, yet coordinating the functionality, structure and component of these materials remains a great challenge. It depends on a comprehensive knowledge of a “real sorption mechanism”. Herein, a ternary mechanism for U(VI) uptake in metal–organic frameworks was reported. Analogous MIL-100s (Al, Fe, Cr) were prepared and studied for their ability to sequestrate U(VI) from aqueous solutions. As a result, MIL-100(Al) performed the best among the tested materials, and MIL-100(Cr) performed the worst. The nuclear magnetic resonance technique combined with energy-dispersive X-ray spectroscopy and zeta potential measurement reveal that U(VI) uptake in the three metal–organic frameworks involves different mechanisms. Specifically, hydrated uranyl ions form outer-sphere complexes in the surface of MIL-100s (Al, Fe) by exchanging with hydrogen ions of terminal hydroxyl groups (Al-OH₂, Fe-OH₂), and/or, hydrated uranyl ions are bound directly to Al(III) center in MIL-100(Al) through a strong inner-sphere coordination. For MIL-100(Cr), however, the U(VI) uptake is attributed to electrostatic attraction. Besides, the sorption mechanism is also pH and ionic strength dependent. The present study suggests that changing metal center of metal–organic frameworks and sorption conditions alters sorption mechanism, which helps to construct effective metal–organic frameworks-based sorbents for water purification.

关键词： U(VI) metal–organic frameworks adsorption mechanism metal node